| Name | Profession | Movie or TV appearance | Has Smoked IRL (In Real Life) | Quit |
| Angela Alvarado | actress | Yes(G) | ||
| Magali Alvarado | actress | Yes | ||
| Trini Alvarado | actress | Yes | ||
| Anne Alvaro | actress | Yes | ||
| Flora María Álvaro | actress | Yes | ||
| Elda Alvigini | actress | ?Yes? | ||
| Anicée Alvina | actress | Yes | ||
| Magali Amadei | actress | Yes | ||
| Amala | actress | Yes | ||
| Zeenat Aman | actress | Yes | ||
| Gaia Bermani Amaral | actress | Yes | ||
| Lauren Ambrose | actress | Yes | ||
| Alessandra Ambrosio | model | Yes? | ||
| Rachel Ames | actress | Yes | ||
| Ramsay Ames | actress | Yes | ||
| Diana Amft | actress | Yes | ||
| Mädchen Amick | actress | Yes | No? | |
| Mervat Amin | actress | Yes | ||
| Suzy Amis | actress | Yes | ||
| Claudia Amm | actress | Yes | ?Yes? | |
| Anna Ammirati | actress | ?Yes? | ||
| Sandra Amodio | actress | Yes | ||
| Sonia Amori | actress | Yes | ||
| Emma Amos | actress | Yes | ||
| Tori Amos | musician | ?Yes? | ||
| Isabel Ampudia | actress | Yes | ||
| Nikki Amuka-Bird | actress | Yes | ||
| Eva Amurri | actress | Yes | No? | |
| Susie Amy | actress | Yes | ||
| Anahí | actress | ?Yes? | ||
| Anastacia | singer | ?Yes? | ||
| Elena Anaya | actress | Yes | ||
| Susan Anbeh | actress | Yes | ||
| Ronni Ancona | actress | Yes(G) | Yes? | |
| Mini Anden | actress | Yes | ||
| Andrea Anders | actress | Yes? | ||
| Luana Anders | actress | Yes | ||
| Merry Anders | actress | Yes | ||
| Isa Andersen | actress | Yes | ||
| Lotte Andersen | actress | Yes |